Usually a jammed calliper piston is caused by the build up of brake dust solidifying on the exposed piston and jamming as the piston is pushed back into the calliper body.
If I read correctly, the problem is the piston jammed OUT? In this instance the best thing to do is remove the calliper and remove all the pistons, give it a good clean and reassemble.
If you don't want to fit new seals etc (which isn't always necessary)careful about what you spray at the calliper. Sometimes it is possible to twist the piston slightly clockwise/anticlockwise using various gubbins but be super careful not to damage the piston surface. The piston may be jammed as it has cocked over. C clamp vise grips are useful to pull the piston back in SLIGHTLY before using compressed air to get them out.
When everything is clean and new the whole process is easy. When it comes to things which are stuck sometimes the cheaper option is to pay someone who has a few clues to fix it. You may be able to do it yourself. You may be able to root it yourself.
If you can afford to learn the hard way are prepared to risk it have a go. Either way you'll learn something.
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