From the rimlock comment I take it it's not a tubeless setup... so the most likely cause is the rimlock is either on the piss or it's the wrong size.
Just peel one side off and have a look to see if it's been sitting correctly, if it looks OK pull it out and check it's not damaged.
Edit: some people put a valve stem nut inside to help prevent the stem being pulled out when the tube "walks" inside the tyre. I didn't, but I never put one on the outside either, for the same reason.
Go soothingly on the grease mud, as there lurks the skid demon
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