Roger, from what you have described, I reckon the bubbling is from steam coming out of the plaster. I don't think the 250 for an hour is enough. Have a look at 2 stroke stuffing when he did his castings, there are a couple of youtubes. I think he observed that 400 was too hot (cracking) and was aiming for a bit less, say 350. However, he also commented that they were held at this temp for a week or so, which maybe over the top.
Also, your timing is good re plaster moulding. We are playing with a different cylinder head for a KTM 250 in a kart. Typically, the standard head can't be turned round so the coolant exits at the rear. Well it can be, but results in total short circuiting of the coolant thru the cylinder and head, and some even do it...why??? So we are doing a 2 piece head with a turned combustion chamber, backed up with a cast cover which provides a natty cooling path and has a rear exit.
Have printed up 2 parts, using stuff called Polycast (see
https://www.youtube.com/watch?v=NBxp...ature=emb_logo). The plan is to cast one using your 50:50 plaster (of paris) & sand mix. The other we will try some stuff called Omega Gold Star (
https://www.goldstarpowders.com/products/ip-omega).
Here's a couple of pics of how we'll do it, with the down sprue going down the centre.

Great to see you are splashing hot metal around.

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