depends totally on what the "stuff" is. if its the liquid nugget shoe polish stuff then soap and water and a scrubbing brush will shift it pretty easilly.
If they used a silicone based tyre shine then you need slightly more agressive tactics. .
To clean the stuff off of cage paintwork I use a product called prepsol which is basicly a weakened form of car paint thinners.
be careful with it and it wont effect the rubber.
But even so I'd still use dishwashing liquid in VERY hot water afterwards and scrub the tyre
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