I have a little inside knowledge (I work for BP, not pumping gas). I agree that you won't get any benefit on a stock 250 from higher octane fuel. Some people wouldn't even notice the difference between 91 and 95. If you raised the compression of your motor it might make more power, but you then might run into problems with detonation, so then you would need higher octane fuel. I would say at least 90% of people think that if you put avgas in a street car/bike it will instantly turn into a rocketship. And don't get me started on confusing avgas with jetfuel. Very frustrating for a fuel nerd.If you are having problems on pump fuel with a stock bike, a tune might help.
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