That's a good goal to have. Any air rifle suitable for this process would likely require a firearms licence anyway.
The firearms licence process is really quite simple. Get the form and fill it out with personal details and a couple of references. I used my girlfriend and flatmate, but just ask the Police for suggestions if you don't have anyone to mind. Take the form back to them and book in for the 'Mountain Safety Course' which is really just a 'don't look down the barrel and don't point it at your mates' kind of course. Read through the arms code and memorize the 7 rules that are in there. The course is a couple of hours and then a pretty basic multi-choice questionnaire at the end. The police will then schedule a time to interview your references and check your firearms storage.
For storage, I've seen people using all sorts. The tried and true method is the standard wall mount rack. Make sure you use 4 long wood screws that go firmly into a stud and the nogs if on a timber wall. For bonus points, drill out the heads a little so you can't just unscrew them again (can easily be unscrewed by hammering a square head bit into the divot left behind). If on a concrete wall, just use a couple of smallish dynabolts. The best place is inside something like a cupboard or hidden away a bit. Mine has always just been on the wall (once on timber, once on cinder block) in my attached garage with a sheet over it. You'll get brownie points if this is in an area of the house with an alarm and if you can hide the rack behind something. If in doubt, the police are pretty helpful with regards to where is acceptable or preferred.
My sister is a vet who has routinely put down cows with .22s, but the comment she said is 'you've really got to know where to aim'. I assume it's a lot easier with a calf, though. The other thing is being aware that you can't really use the sights properly if you're closer than a couple of meters, you've got to aim high enough to adjust for how high the 'line' of the sights are compared to the line of the bore. Normally this is only about 20-30mm...
If he's not likely to be that interested in shooting then a cheap second hand bolt action with a stainless barrel would be the way to go, something like a Savage or Stirling. Failing that, the Norinco bolt action .22s are reasonable, but I'd imagine they might need a little bit more care with regards to going rusty.
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