Rule of thumb:
Steel is gentle but heavy as a brick.
Alu is light but brittle and hard on reproductive (and other) organs
Ti is heavier than Alu but gentle like steel.
Carbon feels like riding crystallized air but is brittle and very expensive.
Go with Ti if you can afford it. Your prostate will thank you.
It may be a good idea to start with a decent frame and upgrade the groupset and wheels as you go. Don't repeat my mistake and get a grouppie with a granny gear. Helps a lot for those infinite climbs.
Carbon fork and seatpost are worthwhile investments.
"People are stupid ... almost anyone will believe almost anything. Because people are stupid, they will believe a lie because they want to believe it's true, or because they are afraid it might be true. People's heads are full of knowledge, facts, and beliefs, and most of it is false, yet they think it all true ... they can only rarely tell the difference between a lie and the truth, and yet they are confident they can, and so all are easier to fool." -- Wizard's First Rule
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